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Type of publication:Article
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TitleA Statistical Mechanical Theory of First-order Phase Transitions on Crystalline Electrodes
English TitleA Statistical Mechanical Theory of First-order Phase Transitions on Crystalline Electrodes
MESC
Bibtex cite ID
Journal Obzory matematiky, fyziky a informatiky
Year published 2006
Volume 35
Number 3
Pages 21-24
ISSN 1335-4981
Abstract
We briefly discuss a statistical mechanical theory from which voltammogram spikes observed during underpotential deposition (UPD) on electrode surfaces can be obtained. We interpret a voltammogram spike as an averaged result of a first-order phase transition taking place in each of the crystalline domains (crystals) formed on the electrode surface. This allows us to fit the theoretical voltammogram spike to experiment with very good precision. We demonstrate this with the UPD of Cu on Pt(111).
Authors
Medveď, Igor
Huckaby, Dale A.
Topics
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  Based on Aigaion, modifications MD© 2007