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TitleFirst-order phase transitions for an ensemble of finite systems
English TitleFirst-order phase transitions for an ensemble of finite systems
MESC
Bibtex cite ID
Journal Obzory matematiky, fyziky a informatiky
Year published 2006
Volume 35
Number 2
Pages 24-29
ISSN 1335-4981
Abstract
We consider a large ensemble of identical systems in cubic volumes of various sizes. Assuming that each system exhibits a first-order phase transition with a two-phase coexistence, we discuss the cumulative effect of the finite-size effects in the constituent systems of the ensemble. Such an analysis is important in the statistical mechanical description of voltammogram spikes measured in electrochemistry.
Authors
Medveď, Igor
Huckaby, Dale A.
Topics
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  Based on Aigaion, modifications MD© 2007